Michelson-Morley Experiment
Maxwell's equations of electromagnetism yield solutions for travelling electromagnetic waves. The speed of light comes naturally out of these solutions. A natural question to ask was what reference frame that this speed is to be measured in.
The Michelson-Morley experiment was a precision measurement which showed that the speed was independent of the relative motion of the observer. This then suggested that the speed of light is independent of the observer, and formed one of the postulates of the special theory of relativity.
For a detailed explanation of the Michelson-Morley experiment see Claustrophobic Physics Michelson-Morley experiment.
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